Herein, a facile and general electroreductive deuteration of unactivated alkyl halides (X = Cl, Br, I) or pseudo-halides (X = OMs) using D 2 O as the economical deuterium source was reported. In ...
Herein, we demonstrate that unactivated primary and secondary alkyl bromides are competent precursors for generating tertiary alkyl coupling partners via Ni–H-mediated chain-walking (Fig. 1e). To ...
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